3-hexenyl salicylate is an odorant occurring in a colorless liquid form which is widely used as a perfuming, flavoring, and fragrance agent in the personal care, cosmetics, and toiletries industries. It is well-known for its fresh and sweet floral aroma, which is also termed as green, metallic, and herbal balsam. While the ingredient is naturally available, it can also be synthesized and is the ester derivative of benzoic acid. Its CAS Number is 65405-77-8 and molecular formula C13H16O3.
Salient
properties of 3-hexenyl salicylate include its high boiling point and density
which allow it to stay stable in normal environments & temperatures and its
long-lasting floral fragrance, which make it a highly desirable ingredient in
various products apart from perfumes. These include emollients and skin
cleaning agents such as antiperspirants or deodorants, creams & lotions,
talcum powders, tablet & liquid soaps, shampoos, hair conditioners, bath
& shower gels, liquid detergents, fabric softeners, and incense & pot
pourri, among others. It also helps that the product is insoluble in water and
soluble in alcohol. Different products comprise a different mix of 3-hexenyl
salicylate, and as such, the ingredient can be classified by its average
percentage used in products which differs from a minimum of around 0.12% to an
average of around 1.2% and a maximum of 12%.
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There are
no major disadvantages associated with 3-hexenyl salicylate, which points to a
bright financial outlook. However, the product can cause skin, eye, and
respiratory irritation, especially in people with skin allergies or
extra-sensitive skin. This is apart from the product being designated hazardous
to aquatic environment and life. There are also a few substitutes available in
the market, especially some with a lower odor threshold value such as 3-hexenyl
benzoate. However, these do not present a major threat in the foreseeable
future. 3-hexenyl salicylate is an established and popular flavor with
well-known properties, which is expected to help its global market remain stable
in the next few years and expand at a rate corresponding to the personal care,
cosmetics, and toiletries sectors. On a global level, these are expected to
expand at an average rate of 5% per annum. Accordingly, 3-hexenyl salicylate
can be classified by these end-user industries.
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In terms
of ingredient availability, suppliers of 3-hexenyl salicylate are spread across
the world with no particular region having an upper hand. But the future demand
for its end-products like perfumes, creams and shampoos etc. is likely to
increase at a higher rate in developing countries in Asia Pacific and Latin
America over traditional markets in developed countries in Europe and North
America. This change is a direct result of the sluggish population and income
growth in developed countries, compared to the higher disposable incomes now
witnessed in developing ones. In the meantime, the Middle East & Africa
will continue to be a slow but stable market. The global 3-hexenyl salicylate
market is distributed by region over Asia Pacific, Latin America, Europe, North
America, and Middle East & Africa.
Among the
suppliers, some of the better-known companies include Germany-based A.C.S.
International and abcr GmbH, U.S.-based Advanced Biotech, Apiscent Labs,
Bedoukian Research, Berjé, Sigma-Aldrich, and Parchem, Europe’s Azelis, French
Charabot and PCW France, U.K.-based SRS Aromatics, India-based Biosynth, and
China-based Shanghai Ruizheng Chemical Technology Co. Ltd., Simagchem Corp.,
and Shanghai Hungsun Chemical Co. Ltd.
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